The self-titled disc, produced by Mark Nevers (Lambchop, Calexico, Candi Staton) and Charlie Louvin, was recorded in Spring/Summer 2006 in Nashville. It features guest performances by Elvis Costello, Jeff Tweedy, Will Oldham, Tom T. Hall, George Jones, Bobby Bare Sr., Tift Merritt, Marty Stuart, David Kilgour, and members of Bright Eyes, Lambchop, Superchunk, Blanche and Clem Snide, among others.

The album features several Louvin Brothers classics as well as country favorites first popularized by Jimmie Rodgers, the Delmore Brothers, the Carter Family, and the Monroe Brothers. Charlie also has included a moving tribute to his late brother Ira, with whom he formed the Louvin Brothers in 1940. (Ira Louvin died in a car accident in 1965, at age 41.)